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Whole seeds of Bauhinia variegata L. (Fabaceae) as an efficient biocatalyst for benzyl alcohol preparations from benzaldehydes
| dc.creator | Demmel, Gabriela Inés | |
| dc.creator | Bordón, Daniela L. | |
| dc.creator | Vázquez, Ana María | |
| dc.creator | Decarlini, María Florencia | |
| dc.creator | Díaz Panero, Mariángeles | |
| dc.creator | Rossi, Laura I. | |
| dc.creator | Aimar, Mario Leandro | |
| dc.date | 2021-07-23 | |
| dc.identifier | http://pa.bibdigital.ucc.edu.ar/3320/1/A_Demmel_Bordon_Vazquez.pdf | |
| dc.description | Whole seeds of Bauhinia variegata L. (Fabaceae) were utilized as a biological reducer to transform benzaldehyde into benzyl alcohol. The effects of some variables such as temperature, the load of substrate and co-solvent, were established to optimize the reductive process. Utilizing the optimal reaction conditions, a laboratory-scale reaction (final concentration of the substrate: 21.2 mM) was performed to obtain benzyl alcohol (conversion: 95%; isolated yield: 49%; productivity: 1.11 g L−1 or 0.046 g L−1h−1 of benzyl alcohol). In addition, using these optimal conditions, fourteen substituted benzaldehydes were reduced, with a conversion achieved to their corresponding benzyl alcohols ranging from 62% to >99% (isolated yields from 7% to 70%). Moreover, useful building blocks by the synthesis of the drugs and important commercial products were also obtained. The scope, limitations and advantages of this new biocatalytic synthetic method are also discussed. | |
| dc.description | Fil: Demmel, Gabriel I. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina | |
| dc.description | Fil: Bordón, Daniela L. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina | |
| dc.description | Fil: Vázquez, Ana M. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina | |
| dc.description | Fil: Decarlini, María F. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina | |
| dc.description | Fil: Díaz Panero, Mariángeles. Universidad Católica de Córdoba. Facultad de Ciencias Químicas; Argentina | |
| dc.description | Fil: Rossi, Laura I. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina | |
| dc.description | Fil: Rossi, Laura I. Instituto de Investigaciones en Físico-Química de Córdoba (INFIQC-CONICET); Argentina | |
| dc.description | Fil: Aimar, Mario L. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina | |
| dc.format | application/pdf | |
| dc.language | spa | |
| dc.publisher | Taylor and Francis Ltd. | |
| dc.relation | http://pa.bibdigital.ucc.edu.ar/3320/ | |
| dc.relation | https://www.tandfonline.com/doi/full/10.1080/10242422.2021.1956910 | |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1080/10242422.2021.1956910 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.rights | https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es | |
| dc.source | Demmel, Gabriela Inés ORCID: https://orcid.org/0000-0002-6939-1391 <https://orcid.org/0000-0002-6939-1391>, Bordón, Daniela L. ORCID: https://orcid.org/0000-0001-5211-6564 <https://orcid.org/0000-0001-5211-6564>, Vázquez, Ana María ORCID: https://orcid.org/0000-0002-8466-3471 <https://orcid.org/0000-0002-8466-3471>, Decarlini, María Florencia ORCID: https://orcid.org/0000-0002-9093-6990 <https://orcid.org/0000-0002-9093-6990>, Díaz Panero, Mariángeles, Rossi, Laura I. and Aimar, Mario Leandro ORCID: https://orcid.org/0000-0001-8547-7198 <https://orcid.org/0000-0001-8547-7198> (2021) Whole seeds of Bauhinia variegata L. (Fabaceae) as an efficient biocatalyst for benzyl alcohol preparations from benzaldehydes. Biocatalysis and Biotransformation. ISSN 1024-2422 | |
| dc.subject | QD Química | |
| dc.title | Whole seeds of Bauhinia variegata L. (Fabaceae) as an efficient biocatalyst for benzyl alcohol preparations from benzaldehydes | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:ar-repo/semantics/artículo |
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