dc.contributor.author | Torres R.B. | |
dc.contributor.author | Hoga H.E. | |
dc.contributor.author | Magalhaes J.G. | |
dc.contributor.author | Volpe P.L.O. | |
dc.date.accessioned | 2019-08-20T00:12:04Z | |
dc.date.available | 2019-08-20T00:12:04Z | |
dc.date.issued | 2009 | |
dc.identifier.citation | TORRES, Ricardo Belchior; HOGA, H. E.; MAGALHÃES, Jucélio Gobbi; VOLPE, Pedro Luiz Onófrio. Volumetric Properties of Chloroalkanes + Amines Mixtures: Theoretical Analysis Using the ERAS Model. International Journal of Thermophysics, v. 30, n. 4, p. 1202-1212, 2009. | |
dc.identifier.issn | 0195-928X | |
dc.identifier.uri | https://repositorio.fei.edu.br/handle/FEI/1738 | |
dc.description.abstract | In this study, experimental data of excess molar volumes of {dichloromethane (DCM), or trichloromethane (TCM) + n-butylamine (n-BA), or +s-butylamine (s-BA), or +t-butylamine (t-BA), or +diethylamine (DEA), or +triethylamine (TEA)} mixtures as a function of composition have been used to test the applicability of the extended real associated solution model (ERAS-Model). The values of the excess molar volume were negative for (DCM + t-BA, or +DEA, or +TEA and TCM + n-BA, or +s-BA, or +DEA, or +TEA) mixtures and present sigmoid curves for (DCM + n-BA, or +s-BA) mixtures over the complete mole-fraction range. The agreement between theoretical and experimental results is discussed in terms of cross-association between the components present in the mixtures. © 2009 Springer Science+Business Media, LLC. | |
dc.relation.ispartof | International Journal of Thermophysics | |
dc.rights | Acesso Restrito | |
dc.title | Volumetric properties of chloroalkanes + amines mixtures: Theoretical analysis using theERAS-Model | |
dc.type | Artigo | |